高温固体氧化物电解池应用研究进展

doi:10.12096/j.2096-4528.pgt.22183

发电技术 ›› 2023, Vol. 44 ›› Issue (3): 361-372.DOI: 10.12096/j.2096-4528.pgt.22183

• 绿氢制备-存储-多场景应用关键技术 • 上一篇下一篇

高温固体氧化物电解池应用研究进展

胡轶坤, 曹军文, 张文强, 于波, 王建晨, 陈靖

清华大学核能与新能源技术研究院，北京市海淀区 100084

收稿日期:2023-02-10 出版日期:2023-06-30 发布日期:2023-06-30
通讯作者: 于波
作者简介:胡轶坤(1997)，男，科研助理，研究方向为固体氧化物燃料电池/电解池制备及多样化应用，2544310261@qq.com；
曹军文(1997)，男，博士研究生，研究方向为固体氧化物燃料电池/电解池制备及多样化应用；
张文强(1978)，男，博士，副研究员，研究方向为高温固体氧化物电解池/燃料电池；
于波(1975)，女，博士，教授，研究方向为核能制氢、清洁能源和碳基能源高效转化利用，本文通信作者，cassy_yu@tsinghua.edu.cn；
王建晨(1963)，男，硕士，教授，研究方向为核化学化工。
基金资助:
国家自然科学基金项目(91645126);清华大学自主科研计划项目(2018Z05JZY010);清华-MIT-剑桥低碳能源大学联盟种子基金项目(201LC004)

Application Research Progress of High Temperature Solid Oxide Electrolysis Cell

Yikun HU, Junwen CAO, Wenqiang ZHANG, Bo YU, Jianchen WANG, Jing CHEN

Institute of Nuclear and New Energy Technology, Tsinghua University, Haidian District, Beijing 100084, China

Received:2023-02-10 Published:2023-06-30 Online:2023-06-30
Contact: Bo YU
Supported by:
National Natural Science Foundation of China(91645126);Tsinghua University Initiative Scientific Research Program(2018Z05JZY010);Tsinghua-MIT-Cambridge Low Carbon Energy University Alliance Seed Fund Program(201LC004)

摘要/Abstract

摘要：

高温固体氧化物电解池(solid oxide electrolysis cell，SOEC)是一种能量转化效率高、反应速率快、应用场景广的新型高效电化学能量转化装置，在低成本绿氢制备、高附加值含碳化学品制备、氮氧化物处理、合成氨等领域具有广阔应用前景，有望在能源、化工、交通等领域的低碳化转型发挥重要作用。结合SOEC在制氢、制油、氮化物处理和制氨等领域的最新进展，对SOEC发展现状进行了系统归纳，并对未来发展需要重点关注的方向进行了展望。

关键词: 氢能, 制氢, 固体氧化物电解池(SOEC), 电化学, 合成氨

Abstract:

High temperature solid oxide electrolysis cell (SOEC) is a new type of high-efficiency electrochemical energy transfer device with high energy transfer efficiency, high reaction rate and wide application scenarios. It has enormous potential in the fields including production of low-cost green hydrogen and carbonaceous product with high added values. Nitrogen oxide treatment _{and ammonia synthesis may also be a promising direction of application. SOEC is expected to play an important role in the low-carbon transformation of energy, chemical industry, transportation and other fields. Based on the latest progress of SOEC in the fields of hydrogen production, oil production, nitride treatment and ammonia production, the development status of SOEC was systematically summarized, and the key directions for future development were prospected.}

Key words: hydrogen energy, hydrogen production, solid oxide electrolysis cell (SOEC), electrochemistry, synthetic ammonia

中图分类号:

TK 91

胡轶坤, 曹军文, 张文强, 于波, 王建晨, 陈靖. 高温固体氧化物电解池应用研究进展[J]. 发电技术, 2023, 44(3): 361-372.

Yikun HU, Junwen CAO, Wenqiang ZHANG, Bo YU, Jianchen WANG, Jing CHEN. Application Research Progress of High Temperature Solid Oxide Electrolysis Cell[J]. Power Generation Technology, 2023, 44(3): 361-372.

图/表 8

图1 SOEC结构示意图

Fig. 1 Structure of SOEC

图2 常压下电解水和二氧化碳的热平衡关系

Fig. 2 Thermal equilibrium relationship of H2O and CO2 electrolysis at atmospheric pressure

图3 不同类型的SOEC

Fig. 3 Different types of SOEC

图4 各种新电极结构示意图

Fig. 4 Schematic diagrams of various new electrode structures

图5 纳米合成电极组成的SOEC的跨区域图像

Fig. 5 Cross-sectional images of SOEC with nanocomposite electrode

图6 CO2电化学还原协同烷烃分子电化学氧化制烯烃

Fig. 6 Alkene production via electrochemical reduction of CO2 and oxidation of alkane

图7 2种不同类型SOEC电解制氨反应原理

Fig. 7 Reaction principles of two different types of SOEC electrolysis for ammonia production

图8 清洁能源耦合高温电解技术路线图

Fig. 8 Clean energy coupling with high temperature electrolysis technology roadmap

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高温固体氧化物电解池应用研究进展

Application Research Progress of High Temperature Solid Oxide Electrolysis Cell

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