高温固体氧化物电解池应用研究进展

doi:10.12096/j.2096-4528.pgt.22183

发电技术 ›› 2023, Vol. 44 ›› Issue (3): 361-372.DOI: 10.12096/j.2096-4528.pgt.22183

• 绿氢制备-存储-多场景应用关键技术 • 上一篇下一篇

高温固体氧化物电解池应用研究进展

胡轶坤, 曹军文, 张文强, 于波, 王建晨, 陈靖

清华大学核能与新能源技术研究院，北京市海淀区 100084

收稿日期:2023-02-10 出版日期:2023-06-30 发布日期:2023-06-30
通讯作者: 于波
作者简介:胡轶坤(1997)，男，科研助理，研究方向为固体氧化物燃料电池/电解池制备及多样化应用，2544310261@qq.com；
曹军文(1997)，男，博士研究生，研究方向为固体氧化物燃料电池/电解池制备及多样化应用；
张文强(1978)，男，博士，副研究员，研究方向为高温固体氧化物电解池/燃料电池；
于波(1975)，女，博士，教授，研究方向为核能制氢、清洁能源和碳基能源高效转化利用，本文通信作者，cassy_yu@tsinghua.edu.cn；
王建晨(1963)，男，硕士，教授，研究方向为核化学化工。
基金资助:
国家自然科学基金项目(91645126);清华大学自主科研计划项目(2018Z05JZY010);清华-MIT-剑桥低碳能源大学联盟种子基金项目(201LC004)

Application Research Progress of High Temperature Solid Oxide Electrolysis Cell

Yikun HU, Junwen CAO, Wenqiang ZHANG, Bo YU, Jianchen WANG, Jing CHEN

Institute of Nuclear and New Energy Technology, Tsinghua University, Haidian District, Beijing 100084, China

Received:2023-02-10 Published:2023-06-30 Online:2023-06-30
Contact: Bo YU
Supported by:
National Natural Science Foundation of China(91645126);Tsinghua University Initiative Scientific Research Program(2018Z05JZY010);Tsinghua-MIT-Cambridge Low Carbon Energy University Alliance Seed Fund Program(201LC004)

摘要/Abstract

摘要：

高温固体氧化物电解池(solid oxide electrolysis cell，SOEC)是一种能量转化效率高、反应速率快、应用场景广的新型高效电化学能量转化装置，在低成本绿氢制备、高附加值含碳化学品制备、氮氧化物处理、合成氨等领域具有广阔应用前景，有望在能源、化工、交通等领域的低碳化转型发挥重要作用。结合SOEC在制氢、制油、氮化物处理和制氨等领域的最新进展，对SOEC发展现状进行了系统归纳，并对未来发展需要重点关注的方向进行了展望。

关键词: 氢能, 制氢, 固体氧化物电解池(SOEC), 电化学, 合成氨

Abstract:

High temperature solid oxide electrolysis cell (SOEC) is a new type of high-efficiency electrochemical energy transfer device with high energy transfer efficiency, high reaction rate and wide application scenarios. It has enormous potential in the fields including production of low-cost green hydrogen and carbonaceous product with high added values. Nitrogen oxide treatment _{and ammonia synthesis may also be a promising direction of application. SOEC is expected to play an important role in the low-carbon transformation of energy, chemical industry, transportation and other fields. Based on the latest progress of SOEC in the fields of hydrogen production, oil production, nitride treatment and ammonia production, the development status of SOEC was systematically summarized, and the key directions for future development were prospected.}

Key words: hydrogen energy, hydrogen production, solid oxide electrolysis cell (SOEC), electrochemistry, synthetic ammonia

中图分类号:

TK 91

胡轶坤, 曹军文, 张文强, 于波, 王建晨, 陈靖. 高温固体氧化物电解池应用研究进展[J]. 发电技术, 2023, 44(3): 361-372.

Yikun HU, Junwen CAO, Wenqiang ZHANG, Bo YU, Jianchen WANG, Jing CHEN. Application Research Progress of High Temperature Solid Oxide Electrolysis Cell[J]. Power Generation Technology, 2023, 44(3): 361-372.

图/表 8

图1 SOEC结构示意图

Fig. 1 Structure of SOEC

图2 常压下电解水和二氧化碳的热平衡关系

Fig. 2 Thermal equilibrium relationship of H2O and CO2 electrolysis at atmospheric pressure

图3 不同类型的SOEC

Fig. 3 Different types of SOEC

图4 各种新电极结构示意图

Fig. 4 Schematic diagrams of various new electrode structures

图5 纳米合成电极组成的SOEC的跨区域图像

Fig. 5 Cross-sectional images of SOEC with nanocomposite electrode

图6 CO2电化学还原协同烷烃分子电化学氧化制烯烃

Fig. 6 Alkene production via electrochemical reduction of CO2 and oxidation of alkane

图7 2种不同类型SOEC电解制氨反应原理

Fig. 7 Reaction principles of two different types of SOEC electrolysis for ammonia production

图8 清洁能源耦合高温电解技术路线图

Fig. 8 Clean energy coupling with high temperature electrolysis technology roadmap

参考文献 78

1	赵春生，杨君君，王婧，等.燃煤发电行业低碳发展路径研究[J]．发电技术，2021，42(5)：547-553． doi:10.12096/j.2096-4528.pgt.21054
	ZHAO C S， YANG J J， WANG J，et al. Research on low-carbon development path of coal-fired power industry[J]．Power Generation Technology，2021，42(5)：547-553． doi:10.12096/j.2096-4528.pgt.21054
2	张全斌，周琼芳．基于“双碳”目标的中国火力发电技术发展路径研究[J]．发电技术，2023，44(2)：143-154． doi:10.12096/j.2096-4528.pgt.22092
	ZHANG Q B， ZHOU Q F ．Research on the development path of China’s thermal power generation technology based on the goal of “carbon peak and carbon neutralization”[J]．Power Generation Technology，2023，44(2)：143-154． doi:10.12096/j.2096-4528.pgt.22092
3	ZHENG R Y， LIU Z C， WANG Y D，et al ．The future of green energy and chemicals：rational design of catalysis routes[J]．Joule，2022，6(6)：1148-1159． doi:10.1016/j.joule.2022.04.014
4	董瑞，高林，何松，等．CCUS技术对我国电力行业低碳转型的意义与挑战[J]．发电技术，2022，43(4)：523-532． doi:10.12096/j.2096-4528.pgt.22053
	DONG R， GAO L， HE S，et al ．Significance and challenges of CCUS technology for low-carbon transformation of China’s power industry[J]．Power Generation Technology，2022，43(4)：523-532． doi:10.12096/j.2096-4528.pgt.22053
5	HAUCH A， KÜNGAS R， BLENNOW P，et al ．Recent advances in solid oxide cell technology for electrolysis[J]．Science，2020，370(6513)：6118． doi:10.1126/science.aba6118
6	ZHAO C H， LI Y F， ZHANG W Q，et al ．Heterointerface engineering for enhancing the electrochemical performance of solid oxide cells[J]．Energy & Environmental Science，2020，13(1)：53-85． doi:10.1039/c9ee02230a
7	曹军文，郑云，张文强，等．能源互联网推动下的氢能发展[J]．清华大学学报(自然科学版)，2021，61(4)：302-311． doi:10.16511/j.cnki.qhdxxb.2021.25.007
	CAO J W， ZHENG Y， ZHANG W Q，et al ．Hydrogen energy development driven by the energy internet[J]．Journal of Tsinghua University (Science and Technology)，2021，61(4)：302-311． doi:10.16511/j.cnki.qhdxxb.2021.25.007
8	曹军文，覃祥富，耿嘎，等．氢气储运技术的发展现状与展望[J]．石油学报(石油加工)，2021，37(6)：1461-1478． doi:10.3969/j.issn.1001-8719.2021.06.026
	CAO J W， QIN X F， GENG G，et al ．Current status and prospects of hydrogen storage and transportation technology[J]．Acta Petrolei Sinica (Petroleum Processing Section)，2021，37(6)：1461-1478． doi:10.3969/j.issn.1001-8719.2021.06.026
9	曹军文，张文强，李一枫，等．中国制氢技术的发展现状[J]．化学进展，2021，33(12)：2215-2244． doi:10.7536/PC201128
	CAO J W， ZHANG W Q， LI Y F，et al ．Current status of hydrogen production in China[J]．Progress in Chemistry，2021，33(12)：2215-2244． doi:10.7536/PC201128
10	ZHENG Y， WANG J C， YU B，et al ．A review of high temperature co-electrolysis of H₂O and CO₂ to produce sustainable fuels using solid oxide electrolysis cells (SOECs)：advanced materials and technology[J]．Chemical Society Reviews，2017，46(5)：1427-1463． doi:10.1039/c6cs00403b
11	LI Y F， ZHANG W Q， ZHENG Y，et al ．Controlling cation segregation in perovskite-based electrodes for high electro-catalytic activity and durability[J]．Chemical Society Reviews，2017，46(20)：6345-6378． doi:10.1039/c7cs00120g
12	ZHENG Y， CHEN Z W， ZHANG J J ．Solid oxide electrolysis of H₂O and CO₂ to produce hydrogen and low-carbon fuels[J]．Electrochemical Energy Reviews，2021，4(3)：508-517． doi:10.1007/s41918-021-00097-4
13	LI Z H， LI M R， ZHU Z H ．Perovskite cathode materials for low-temperature solid oxide fuel cells：fundamentals to optimization[J]．Electrochemical Energy Reviews，2022，5(2)：263-311． doi:10.1007/s41918-021-00098-3
14	张文强，于波．高温固体氧化物电解制氢技术发展现状与展望[J]．电化学，2020，26(2)：212-229．
	ZHANG W Q， YU B ．Development status and prospects of hydrogen production by high temperature solid oxide electrolysis[J]．Journal of Electrochemistry，2020，26(2)：212-229．
15	刘明义，于波，徐景明．固体氧化物电解水制氢系统效率[J]．清华大学学报(自然科学版)，2009，49(6)：868-871．
	LIU M Y， YU B， XU J M ．Efficiency of solid oxide electrolysis system for hydrogen production[J]．Journal of Tsinghua University (Science and Technology)，2009，49(6)：868-871．
16	EBBESEN S D， JENSEN S H， HAUCH A，et al ．High temperature electrolysis in alkaline cells，solid proton conducting cells，and solid oxide cells[J]．Chemical Reviews，2014，114(21)：10697-10734． doi:10.1021/cr5000865
17	ADLER S B ．Factors governing oxygen reduction in solid oxide fuel cell cathodes[J]．Chemical Reviews，2004，104(10)：4791-4844． doi:10.1021/cr020724o
18	ZHU T L， TROIANI H E， MOGNI L V，et al ．Ni-substituted Sr(Ti, Fe)O₃ SOFC anodes：achieving high performance via metal alloy nanoparticle exsolution[J]．Joule，2018，2(3)：478-496． doi:10.1016/j.joule.2018.02.006
19	RIVA M， KUBICEK M， HAO X F，et al ．Influence of surface atomic structure demonstrated on oxygen incorporation mechanism at a model perovskite oxide[J]．Nature Communications，2018，9(1)：1-9． doi:10.1038/s41467-018-05685-5
20	NIU B B， LU C L， YI W D，et al ．In-situ growth of nanoparticles-decorated double perovskite electrode materials for symmetrical solid oxide cells[J]．Applied Catalysis B：Environmental，2020，270：118842． doi:10.1016/j.apcatb.2020.118842
21	ZHOU Y J， LIN L， SONG Y F，et al ．Pd single site-anchored perovskite cathode for CO₂ electrolysis in solid oxide electrolysis cells[J]．Nano Energy，2020，71：104598． doi:10.1016/j.nanoen.2020.104598
22	DUAN N Q， YANG J J， GAO M R，et al ．Multi-functionalities enabled fivefold applications of LaCo_0.6Ni_0.4O_3- _δ in intermediate temperature symmetrical solid oxide fuel/electrolysis cells[J]．Nano Energy，2020，77：105207． doi:10.1016/j.nanoen.2020.105207
23	PARK S， KIM Y， HAN H，et al ．In situ exsolved Co nanoparticles on Ruddlesden-Popper material as highly active catalyst for CO₂ electrolysis to CO[J]．Applied Catalysis B：Environmental，2019，248：147-156． doi:10.1016/j.apcatb.2019.02.013
24	DEKA D J， GUNDUZ S， FITZGERALD T，et al ．Production of syngas with controllable H₂/CO ratio by high temperature co-electrolysis of CO₂ and H₂O over Ni and Co-doped lanthanum strontium ferrite perovskite cathodes[J]．Applied Catalysis B：Environmental，2019，248：487-503． doi:10.1016/j.apcatb.2019.02.045
25	KIM Y T， SHIKAZONO N ．Investigation of La_0.6Sr_0.4CoO_3- _δ -Gd_0.1Ce_0.9O_2- _δ composite cathodes with different volume ratios by three-dimensional reconstruction[J]．Solid State Ionics，2017，309：77-85． doi:10.1016/j.ssi.2017.07.010
26	DUAN C C， KEE R J， ZHU H Y，et al ．Highly durable，coking and sulfur tolerant，fuel-flexible protonic ceramic fuel cells[J]．Nature，2018，557：217-222． doi:10.1038/s41586-018-0082-6
27	LI M R， ZHAO M W， LI F，et al ．A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 ℃[J]．Nature Communications，2017，8(1)：1-9． doi:10.1038/ncomms13990
28	BAE K， JANG D Y， CHOI H J，et al ．Demonstrating the potential of yttrium-doped barium zirconate electrolyte for high-performance fuel cells[J]．Nature Communications，2017，8(1)：1-9． doi:10.1038/ncomms14553
29	BOLDRIN P， RUIZ-TREJO E， MERMELSTEIN J，et al ．Strategies for carbon and sulfur tolerant solid oxide fuel cell materials, incorporating lessons from heterogeneous catalysis[J]．Chemical Reviews，2016，116(22)：13633-13684． doi:10.1021/acs.chemrev.6b00284
30	LV H F， LIN L， ZHANG X M，et al ．Promoting exsolution of RuFe alloy nanoparticles on Sr₂Fe_1.4Ru_0.1-Mo_0.5O_6- _δ via repeated redox manipulations for CO₂ electrolysis[J]．Nature Communications，2021，12：1-11． doi:10.1038/s41467-021-26001-8
31	SONG Y F， ZHOU S， DONG Q，et al ．Oxygen evolution reaction over the AU/YSZ interface at high temperature[J]．Angewandte Chemie，2019，58(14)：4617-4621． doi:10.1002/anie.201814612
32	IRVINE J T S， NEAGU D， VERBRAEKEN M C，et al ．Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers[J]．Nature Energy，2016，1：15014． doi:10.1038/nenergy.2015.14
33	WANG F F， KISHIMOTO H， ISHIYAMA T，et al ．A review of sulfur poisoning of solid oxide fuel cell cathode materials for solid oxide fuel cells[J]．Journal of Power Sources，2020，478：228763． doi:10.1016/j.jpowsour.2020.228763
34	AZIZ A J A， BAHARUDDIN N A， SOMALU M R，et al ．Review of composite cathodes for intermediate-temperature solid oxide fuel cell applications[J]．Ceramics International，2020，46(15)：23314-23325． doi:10.1016/j.ceramint.2020.06.176
35	PENNER S， GÖTSCH T， KLÖTZER B ．Increasing complexity approach to the fundamental surface and interface chemistry on SOFC anode materials[J]．Accounts of Chemical Research，2020，53(9)：1811-1821． doi:10.1021/acs.accounts.0c00218
36	ZHANG Y F， LIU J J， SINGH M，et al ．Superionic conductivity in ceria-based heterostructure composites for low-temperature solid oxide fuel cells[J]．Nano-Micro Letters，2020，12：178． doi:10.1007/s40820-020-00518-x
37	PAIVA J A E， CAJAS D P C， RODRIGUES F A，et al ．Synthesis and electrical properties of strontium-doped lanthanum ferrite with perovskite-type structure[J]．Ceramics International，2020，46(11)：18419-18427． doi:10.1016/j.ceramint.2020.04.212
38	AFROZE S， KARIM A H， CHEOK Q，et al ．Latest development of double perovskite electrode materials for solid oxide fuel cells：a review[J]．Frontiers in Energy，2019，13(4)：770-797． doi:10.1007/s11708-019-0651-x
39	DUAN C C，KEE R， ZHU H Y，et al ．Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production[J]．Nature Energy，2019，4(3)：230-240． doi:10.1038/s41560-019-0333-2
40	ZHOU Y， GUAN X F， ZHOU H，et al ．Strongly correlated perovskite fuel cells[J]．Nature，2016，534：231-234． doi:10.1038/nature17653
41	GRIMAUD A， HONG W T， SHAO-HORN Y，et al ．Anionic redox processes for electrochemical devices[J]．Nature Materials，2016，15(2)：121-126． doi:10.1038/nmat4551
42	TSVETKOV N， LU Q Y， SUN L X，et al ．Improved chemical and electrochemical stability of perovskite oxides with less reducible cations at the surface[J]．Nature Materials，2016，15(9)：1010-1016． doi:10.1038/nmat4659
43	GRAVES C， EBBESEN S D， JENSEN S H，et al ．Eliminating degradation in solid oxide electrochemical cells by reversible operation[J]．Nature Materials，2015，14(2)：239-244． doi:10.1038/nmat4165
44	SUNTIVICH J， MAY K J， GASTEIGER H A，et al ．A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles[J]．Science，2011，334：1383-1385． doi:10.1126/science.1212858
45	LI T P， WANG T P， WEI T，et al ．Robust anode-supported cells with fast oxygen release channels for efficient and stable CO₂ electrolysis at ultrahigh current densities[J]．Small，2021，17(6)：1-9． doi:10.1002/smll.202007211
46	李建林，梁忠豪，梁丹曦，等．“双碳”目标下绿氢制备及应用技术发展现状综述[J]．分布式能源，2021，6(4)：25-33． doi:10.16513/j.2096-2185.DE.2106531
	LI J L， LIANG Z H， LIANG D X，et al ．Overview of development status of green hydrogen production and application technology under targets of carbon peak and carbon neutrality[J]．Distributed Energy，2021，6(4)：25-33． doi:10.16513/j.2096-2185.DE.2106531
47	KNIBBE R， TRAULSEN M L， HAUCH A，et al ．Solid oxide electrolysis cells：degradation at high current densities[J]．Journal of the Electrochemical Society，2010，157：1209-1217． doi:10.1149/1.3447752
48	WU T， ZHANG W Q， LI Y F，et al ．Micro-/nanohoneycomb solid oxide electrolysis cell anodes with ultralarge current tolerance[J]．Advanced Energy Materials，2018，8(33)：1802203． doi:10.1002/aenm.201802203
49	CAO J W， LI Y F， ZHENG Y，et al ．A novel solid oxide electrolysis cell with micro-/nano channel anode for electrolysis at ultra-high current density over 5 A⋅cm^-2 [J]．Advanced Energy Materials，2022，12(28)：2200899． doi:10.1002/aenm.202200899
50	WU W， DING H P， ZHANG Y Y，et al ．3D self-architectured steam electrode enabled efficient and durable hydrogen production in a proton-conducting solid oxide electrolysis cell at temperatures lower than 600 ℃[J]．Advanced Science，2018，5(11)：1800360． doi:10.1002/advs.201800360
51	SHIMADA H， YAMAGUCHI T， KISHIMOTO H，et al ．Nanocomposite electrodes for high current density over 3 A⋅cm^-2 in solid oxide electrolysis cells[J]．Nature Communications，2019，10(1)：5432． doi:10.1038/s41467-019-13426-5
52	初壮，赵蕾，孙健浩，等．考虑热能动态平衡的含氢储能的综合能源系统热电优化[J]．电力系统保护与控制，2023，51(3)：1-12．
	CHU Z， ZHAO L， SUN J H，et al ．Thermoelectric optimization of an integrated energy system with hydrogen energy storage considering thermal energy dynamic balance[J]．Power System Protection and Control，2023，51(3)：1-12．
53	要点氢能．Bloom在美启动批量SOEC电解槽生产线 [EB/OL]．(2022-11-03)[2022-12-15]．． doi:10.4135/9781544391199.n345
	Hydrogen Point ．Bloom starts SOEC manufacture production line in America[EB/OL]．(2022-11-03)[2022-12-15]．． doi:10.4135/9781544391199.n345
54	Department of Energy ．INFOGRAPHIC：clean hydrogen powered by nuclear energy[EB/OL]．(2022-11-09)[2022-12-25]．．
55	Department of Energy ．4 nuclear power plants gearing up for clean hydrogen production[EB/OL]．(2022-11-09)[2022-12-25]．．
56	科技日报．清华大学固体氧化物电解池制氢系统样机开发项目通过验收[EB/OL]．(2022-07-20)[2022-12-15]．. doi:10.17161/pc.1808.15982
	2&wfr=spider&for=pc ． Science and Technology Daily．SOEC hydrogen producing system prototype development project has passed the acceptance check[EB/OL]．(2022-07-20)[2022-12-15]．. doi:10.17161/pc.1808.15982
	2&wfr=spider&for=pc． doi:10.17161/pc.1808.15982
57	张平，于波，徐景明．核能制氢技术的发展[J]．核化学与放射化学，2011，33(4)：193-203．
	ZHANG P， YU B， XU J M ．Development of the technology for nuclear production of hydrogen[J]．Journal of Nuclear and Radiochemistry，2011，33(4)：193-203．
58	LIU S M， ZHANG W Q， LI Y F，et al ．REBaCo₂O₅₊ _δ (RE=Pr, Nd, and Gd) as promising oxygen electrodes for intermediate-temperature solid oxide electrolysis cells[J]．RSC Advances，2017，7(27)：16332-16340． doi:10.1039/c6ra28005f
59	LIU S M， YU B， ZHANG W Q，et al ．Electrochemical performance of Co-containing mixed oxides as oxygen electrode materials for intermediate-temperature solid oxide electrolysis cells[J]．International Journal of Hydrogen Energy，2016，41(36)：15952-15959． doi:10.1016/j.ijhydene.2016.05.077
60	ZHANG W Q， YU B， XU J M ．Investigation of single SOEC with BSCF anode and SDC barrier layer[J]．International Journal of Hydrogen Energy，2012，37(1)：837-842． doi:10.1016/j.ijhydene.2011.04.049
61	WANG X， YU B， ZHANG W Q，et al ．Microstructural modification of the anode/electrolyte interface of SOEC for hydrogen production[J]．International Journal of Hydrogen Energy，2012，37(17)：12833-12838． doi:10.1016/j.ijhydene.2012.05.093
62	ZHAO C H， LIU X G， ZHANG W Q，et al ．Measurement of oxygen reduction/evolution kinetics enhanced (La, Sr)CoO₃/(La, Sr)₂CoO₄ hetero-structure oxygen electrode in operating temperature for SOCs[J]．International Journal of Hydrogen Energy，2019，44(35)：19102-19112． doi:10.1016/j.ijhydene.2018.04.128
63	LIANG M D， YU B， WEN M F，et al ．Preparation of NiO-YSZ composite powder by a combustion method and its application for cathode of SOEC[J]．International Journal of Hydrogen Energy，2010，35(7)：2852-2857． doi:10.1016/j.ijhydene.2009.05.006
64	LIANG M D， YU B， WEN M F，et al ．Preparation of LSM-YSZ composite powder for anode of solid oxide electrolysis cell and its activation mechanism[J]．Journal of Power Sources，2009，190(2)：341-345． doi:10.1016/j.jpowsour.2008.12.132
65	QIN X F， CAO J W， GENG G，et al ．Solid oxide fuel cell system for automobiles[J]．International Journal of Green Energy，2022：1-10． doi:10.1080/15435075.2022.2065454
66	ZHENG Y， ZHAO C H， WU T，et al ．Enhanced oxygen reduction kinetics by a porous heterostructured cathode for intermediate temperature solid oxide fuel cells[J]．Energy and AI，2020，2：100027． doi:10.1016/j.egyai.2020.100027
67	ZHENG Y， LI Y F， WU T，et al ．Controlling crystal orientation in multilayered heterostructures toward high electro-catalytic activity for oxygen reduction reaction[J]．Nano Energy，2019，62：521-529． doi:10.1016/j.nanoen.2019.05.069
68	ZHENG Y， LI Y F， WU T，et al ．Oxygen reduction kinetic enhancements of intermediate-temperature SOFC cathodes with novel Nd_0.5S_r0.5CoO_3- _δ /Nd_0.8Sr_1.2CoO_4± _δ heterointerfaces[J]．Nano Energy，2018，51：711-720． doi:10.1016/j.nanoen.2018.07.017
69	LI Y F， ZHANG W Q， WU T，et al ．Segregation induced self-assembly of highly active perovskite for rapid oxygen reduction reaction[J]．Advanced Energy Materials，2018，8(29)：1801893． doi:10.1002/aenm.201801893
70	ZHU J X， ZHANG W Q， LI Y F，et al． Enhancing CO 2 catalytic activation and direct electroreduction on in-situ exsolved Fe/MnO _x nanoparticles from (Pr, Ba)₂-Mn_2- _y Fe _y O₅₊ _δ layered perovskites for SOEC cathodes[J]．Applied Catalysis B：Environmental，2020，268：118389 ． doi:10.1016/j.apcatb.2019.118389
71	SKAFTE T L， GUAN Z X， MACHALA M L，et al ．Selective high-temperature CO₂ electrolysis enabled by oxidized carbon intermediates[J]．Nature Energy，2019，4(10)：846-855． doi:10.1038/s41560-019-0457-4
72	YE L T， SHANG Z B， XIE K ．Selective oxidative coupling of methane to ethylene in a solid oxide electrolyser based on porous single-crystalline CeO₂ monoliths[J]．Angewandte Chemie，2022，61(32)：1-8． doi:10.1002/ange.202207211
73	SONG Y F， LIN L， FENG W C，et al ．Interfacial enhancement by γ-Al₂O₃of electrochemical oxidative dehydrogenation of ethane to ethylene in solid oxide electrolysis cells[J]．Angewandte Chemie，2019，58(45)：16043-16046． doi:10.1002/anie.201908388
74	LI W J， LIU X Z， YU H，et al ．La_0.75Sr_0.25Cr_0.5Mn_0.5-O_3- _δ Ce_0.8Sm_0.2O_1.9 as composite electrodes in symmetric solid electrolyte cells for electrochemical removal of nitric oxide[J]．Applied Catalysis B：Environmental，2020，264：118533． doi:10.1016/j.apcatb.2019.118533
75	AMAR I A， LAN R， HUMPHREYS J，et al ．Electrochemical synthesis of ammonia from wet nitrogen via a dual-chamber reactor using La_0.6Sr_0.4Co_0.2Fe_0.8O_3- _δ -Ce_0.8Gd_0.18Ca_0.02O_2- _δ composite cathode[J]．Catalysis Today，2017，286：51-56． doi:10.1016/j.cattod.2016.09.006
76	WANG K H， CHEN H L， LI S D，et al ．Sr _x Ti_0.6Fe_0.4O_3- _δ (x=1.0, 0.9) catalysts for ammonia synthesis via proton-conducting solid oxide electrolysis cells (PCECs)[J]．Journal of Materials Chemistry A，2022，10：24813-24823． doi:10.1039/d2ta01669a
77	JIANG L L， FU X Z ．An ammonia-hydrogen energy roadmap for carbon neutrality：opportunity and challenges in China[J]．Engineering，2021，7(12)：1688-1691． doi:10.1016/j.eng.2021.11.004
78	氢能源网．绿氨制备：世界最大容量电解槽预定 [EB/OL]．(2022-09-16)[2022-12-15]．．
	China-Hydrogen ．Green ammonia production：electrolysis cell with world’s largest capacity preordered[EB/OL]．(2022-09-16)[2022-12-15]．．

[1]	刘玉成, 杨源, 胡宇浩, 李雨航, 赵子泰, 马志勇, 董玉亮. 基于事件树连锁故障推演和证据推理的制氢站设备风险评价[J]. 发电技术, 2024, 45(1): 42-50.
[2]	曹冬惠, 杜冬梅, 何青. 氢储能安全及其检测技术综述[J]. 发电技术, 2023, 44(4): 431-442.
[3]	孔令国, 宫健, 杨士慧, 倪德富, 王士博, 刘闯. DC/DC隔离型制氢电源发展现状与趋势[J]. 发电技术, 2023, 44(4): 443-451.
[4]	宋天琦, 马韵婷, 张智慧. 光伏耦合电解水制氢系统作为虚拟电厂资源的运行模式与经济性分析[J]. 发电技术, 2023, 44(4): 465-472.
[5]	兰宇, 龙妍, 张哲豪, 阮金港. 可再生能源制氢跨省供应的技术经济可行性研究[J]. 发电技术, 2023, 44(4): 473-483.
[6]	吴磊, 彭黎菊, 李爽, 史翊翔, 蔡宁生. 百千瓦级天然气制氢质子交换膜燃料电池热电联产系统稳态特性模拟分析[J]. 发电技术, 2023, 44(3): 350-360.
[7]	赵连鹏, 张振扬, 安刚, 杨申音. 混合冷剂氢液化技术研究进展[J]. 发电技术, 2023, 44(3): 331-339.
[8]	滕越, 赵骞, 袁铁江, 陈国宏. 绿电-氢能-多域应用耦合网络关键技术现状及展望[J]. 发电技术, 2023, 44(3): 318-330.
[9]	张春雁, 窦真兰, 王俊, 朱亮亮, 孙晓彤, 李根蒂. 电解水制氢-储氢-供氢在电力系统中的发展路线[J]. 发电技术, 2023, 44(3): 305-317.
[10]	陈逸文, 赵晋斌, 李军舟, 毛玲, 屈克庆, 魏国庆. 电力低碳转型背景下氢储能的挑战与展望[J]. 发电技术, 2023, 44(3): 296-304.
[11]	李建林, 邵晨曦, 张则栋, 梁忠豪, 曾飞. 氢能产业政策及商业化模式分析[J]. 发电技术, 2023, 44(3): 287-295.
[12]	董辉, 葛维春, 张诗钽, 刘闯, 楚帅. 海上风电制氢与电能直接外送差异综述[J]. 发电技术, 2022, 43(6): 869-879.
[13]	李泽航, 周浩, 李浩秒, 王康丽, 蒋凯. 面向电力系统的液态金属电池储能技术[J]. 发电技术, 2022, 43(5): 760-774.
[14]	李雪临, 袁凌. 海上风电制氢技术发展现状与建议[J]. 发电技术, 2022, 43(2): 198-206.
[15]	朱凯, 张艳红. “双碳”形势下电力行业氢能应用研究[J]. 发电技术, 2022, 43(1): 65-72.

高温固体氧化物电解池应用研究进展

Application Research Progress of High Temperature Solid Oxide Electrolysis Cell

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 78

相关文章 15

编辑推荐

Metrics

本文评价